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Bulky tris(mercaptoimidazolyl)borates: synthesis and molecular structures of the Group 12 metal complexes [TmtBu]MBr (M = Zn, Cd, Hg)

✍ Scribed by White, Jennifer L.; Tanski, Joseph M.; Rabinovich, Daniel


Book ID
120394681
Publisher
The Royal Society of Chemistry
Year
2002
Tongue
English
Weight
152 KB
Volume
15
Category
Article
ISSN
1472-7773

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Metal–Metal Bonds between Group 12 Metal
✍ Matthias Lutz; Bernd Findeis; Matti Haukka; Roland Graff; Tapani A. Pakkanen; Lu πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 188 KB πŸ‘ 1 views

Reaction of the lithium triamidostannate [MeSi[SiMe(2)N(p-Tol)](3)SnLi(OEt(2))] (1) with 0.5 molar equivalents of MCl(2) (M=Zn, Cd, Hg) in toluene afforded the corresponding heterodimetallic complexes [MeSi[SiMe(2)N(p-Tol)](3)Sn](2)M [M=Hg (2), Cd (3), and Zn (4)]. The molecular structures of the me