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The preparation and structure of a germanium-bridged iron carbonyl complex, [(CH3)2Ge]3Fe2(CO)6

✍ Scribed by Brooks, E. H.; Elder, M.; Graham, W. A. G.; Hall, D.


Book ID
126218959
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
253 KB
Volume
90
Category
Article
ISSN
0002-7863

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The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3Β±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri