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Synthesis, structure, and bonding of the bis(phosphenium) ion-dicobalt carbonyl complex Co2(CO)5(.mu.-PN(CH3)CH2CH2NCH3)2

✍ Scribed by Hutchins, L. D.; Light, R. W.; Paine, R. T.


Book ID
127101035
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
890 KB
Volume
21
Category
Article
ISSN
0020-1669

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The triisocyanide ligand CH3C(CH2NC)3 reacts with Cr-acterized by an X-ray structure analysis allowing a direct com-(CO),(THF) depending on the stoichiometry to give the com-parison of the bonding parameters of coordinated and nonplexes CH3C(CH2NC),[CH2NC ~ Cr(C0)5]3-, (x = 1, 2). The coordinated is