The preparation and acetolyses of 5-deuteriated exo-norbornyl brosylates
✍ Scribed by N.H. Werstiuk; R.R. MacDonald; R.W. Ouwehand; W.L. Chan; F.P. Cappelli; J.G. Ballard; R.E. Young; R.E. Massey; G. Timmins
- Book ID
- 104222677
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 184 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
a, B and Y deuteriw isotope effects have been used extensively to probe the nature of the norbornyl cation3(a)-3(i) generated solvolytically. Of special interest has been the work of Uurr et al. 3(c) and Bo&ii( et a1.3(d) which showed that the isotope
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## Abstract The __exo__‐ and __endo__‐irontricarbonyl complexes of 5,6‐dimethylidene‐2‐__exo__‐norbornyl alcohols **10x, 10n**, __p__‐bromobenzenesulfonates **11x, 11n**, acetate **12x** and of the 2,3‐dimethylidene‐7‐__anti__‐norbornyl alcohols **17x, 17n**, __p__‐bromobenzenesulfonates **19x, 19n
## Abstract The solvolysis rates and products of the 6‐__exo__‐substituted 2‐__exo__‐ **1a**‐**1u**, and 2‐__endo__‐norbornyl __p__‐toluenesulfonates **2a**‐**2u**, have been determined. In general, the rate constants for **1** and **2** (log __k__) correlate well with the inductive constants σ of