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The Potentially Hexadentate Isomeric Macrocycles trans- and cis- 6,13-Diethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine and Their Cobalt(III) Complexes: Unexpected Conformational Behavior

✍ Scribed by Bernhardt, Paul V.; Byriel, Karl A.; Kennard, Colin H. L.; Sharpe, Philip C.


Book ID
126215724
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
283 KB
Volume
35
Category
Article
ISSN
0020-1669

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## Abstract Molecular‐mechanics calculations of the sexidentate coordinated complexes of the pendant arm macrocyclic hexaamines __trans__‐ (L^1^) and __cis__‐6,13‐dimethyl‐3,4,8,11‐tetraazacyclotetradecane‐6,13‐diamine (L^2^) reveal that the __trans__‐isomer shows a preference toward small metal io