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Isolation and complexation of the cis isomer of the pendant arm macrocycle 6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine

✍ Scribed by Bernhardt, Paul V.; Comba, Peter; Hambley, Trevor W.; Lawrance, Geoffrey A.; V�rnagy, Katalin


Book ID
120656532
Publisher
The Royal Society of Chemistry
Year
1992
Tongue
English
Weight
689 KB
Volume
3
Category
Article
ISSN
1472-7773

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A Molecular-Mechanics Analysis of Comple
✍ Paul V. Bernhardt; Peter Comba 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 German ⚖ 527 KB

## Abstract Molecular‐mechanics calculations of the sexidentate coordinated complexes of the pendant arm macrocyclic hexaamines __trans__‐ (L^1^) and __cis__‐6,13‐dimethyl‐3,4,8,11‐tetraazacyclotetradecane‐6,13‐diamine (L^2^) reveal that the __trans__‐isomer shows a preference toward small metal io