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The potential energy barrier of the Na2 B 1Πu state

✍ Scribed by Chawla, Gunjit K.; Vedder, H. Joachim; Field, Robert W.

Book ID
120615571
Publisher
American Institute of Physics
Year
1987
Tongue
English
Weight
845 KB
Volume
86
Category
Article
ISSN
0021-9606

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We have used the e\pc:imental energy levels of the B state of Na2 to determine the shape of the potentL1 curve. The potential curve obtained has been used to determine the Fran&-Condon o\rrlnp of the continuum vibrational levels in the B state with bound levels in the ground ekctronic state.

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All quasibound vibrational encr~y levels U' = 27-33 of the NaZ B 'no state arc accessed via a triple resonance C\CitatiOn scheme: cw modulated gain spectroscopy (MCS). Two independent analyses involve a Pad&type near-dissociation representation of the observed energies and non-linear least-squares f