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The possibility of molecular switching: Theoretical study of [(NH3)5Ru-4,4′-bipy-Ru(NH3)5]5+

✍ Scribed by S. Woitellier; J.P. Launay; C. Joachim

Book ID
107942436
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
796 KB
Volume
131
Category
Article
ISSN
0301-0104

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✍ C. Joachim 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 523 KB

Through-ligand electronic coupling in the [ (NH3),Ru"'-1,4dicyanobenzene-Ru"(NH3)5] '+ complex is calculated depending on the donor or acceptor grafted on the benzene. The coupling strength is first discussed, showing that through-dicyanobutadiene is larger than through-I$-dicyanobenzene coupling. W