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Electronic structure, spectrum, and intramolecular electron transfer model of [(NH3)5Ru-(4,4’-bipy)-Ru(NH3)5]5+

✍ Scribed by O. V. Sizova; A. I. Panin; N. V. Ivanova; V. I. Baranovskii

Book ID
110672096
Publisher
SP MAIK Nauka/Interperiodica
Year
1997
Tongue
English
Weight
665 KB
Volume
38
Category
Article
ISSN
0022-4766

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✍ C. Joachim 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 523 KB

Through-ligand electronic coupling in the [ (NH3),Ru"'-1,4dicyanobenzene-Ru"(NH3)5] '+ complex is calculated depending on the donor or acceptor grafted on the benzene. The coupling strength is first discussed, showing that through-dicyanobutadiene is larger than through-I$-dicyanobenzene coupling. W