The linear absorption cross-sections and photodissociation quantum yields for C F 3 N 0 have been measured at the wavelengths 694 3 and 632 8 nm (ruby and He-Ne lasers respectively) in a wide range of total pressure at T = 296 K The secondary reactions following the photolysis of C F 3 N 0 have been
The positive ion chemistry of trifluoronitrosomethane, CF3NO
β Scribed by C.G. Freeman; P.W. Harland; M.J. McEwan
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 507 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0020-7381
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The electronic origin of the A A" +-z A' transition of trifluoronitrosomethane (CFINO) has been reassigned to the very weak feature near 7 17.9 nm in the fluorescence excitation spectrum of the jet-cooled molecule. The prominent torsional progression has been reinpreted and the height of the threefo
The ultraviolet absorption spectrum of CF3CFC102 and the kinetics of the self reactions of CF3CFC1 and CF3CFC102 radicals and the reactions of CFzCFC102 with NO and NO2 have been studied in the gas phase at 295 K by pulse radiolysis/transient UV absorption spectroscopy. The UV absorption cross secti
A laser flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the reaction of O(3P) with CF3NO (kz) as a function of temperature. Our results are described by the Arrhenius expression k z ( T ) = (4.54 ? 0.70) X 10-12exp[(-560 i 46)/T] cm3molecule-'s-' (243 K 5
The kinetics of the reaction of CF,CFHO, radicals with NO was studied by flash photolysis-time-resolved mass spectrometry. From the kinetic growth rate of NO: molecular ions the rate coefficient of the reaction CF,CFHO, + NO -+ CF,CFHO + NO, was determined to be k = (1.31 &-0.30) X 10-l' cm3 molecul