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The Polymerization of Isoprene with sec-Butyllithium in Hexane

✍ Scribed by Roovers, J. E. L.; Bywater, S.

Book ID
127334106
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
443 KB
Volume
1
Category
Article
ISSN
0024-9297

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A mathematical model for polymerization of isoprene with n-butyllithium in benzene
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## Abstract Isoprene was polymerized in batch reactors by use of bottle polymerization techniques at 20Β°, 30Β°, and 40Β°C at concentrations from 1 to 5 molar. Isoprene and __n__‐butyllithium conversions and molecular weight distributions were determined for different reaction times. Rate equations fo

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Polymerization of isoprene (IP) with alkyllithium (RLi) catalysts in the presence of amines such as triethylamine (TEA), 1,2-dipiperidinoethane (DPPE) and N,N,N@,N@-tetramethyldiaminoalkanes where 4 and 6 (TMDAA)] has been studied. By adding the amines, the polymerization rate of IP was accelerated