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Kinetics of polymerization of isoprene with butyllithium

✍ Scribed by Guyot, A. ;Vialle, J.

Book ID
104534405
Publisher
Wiley (John Wiley & Sons)
Year
1968
Tongue
English
Weight
217 KB
Volume
6
Category
Article
ISSN
0449-2986

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A mathematical model for polymerization
A mathematical model for polymerization of isoprene with n-butyllithium in benzene
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## Abstract Isoprene was polymerized in batch reactors by use of bottle polymerization techniques at 20Β°, 30Β°, and 40Β°C at concentrations from 1 to 5 molar. Isoprene and __n__‐butyllithium conversions and molecular weight distributions were determined for different reaction times. Rate equations fo

Effects of amines on the polymerization
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Polymerization of isoprene (IP) with alkyllithium (RLi) catalysts in the presence of amines such as triethylamine (TEA), 1,2-dipiperidinoethane (DPPE) and N,N,N@,N@-tetramethyldiaminoalkanes where 4 and 6 (TMDAA)] has been studied. By adding the amines, the polymerization rate of IP was accelerated