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The Polymerization of Acetylenes by Nickel Halide—Tertiary Phosphine Complexes

✍ Scribed by Daniels, W. E.

Book ID
126886747
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
400 KB
Volume
29
Category
Article
ISSN
0022-3263

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Homogeneous polymerization of norbornene
Homogeneous polymerization of norbornene catalyzed by ruthenium complex–tertiary phosphine system
✍ Hiraki, Katsuma ;Kuroiwa, Akihiko ;Hirai, Hidefumi 📂 Article 📅 1971 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 526 KB

## Abstract Norbornene is polymerized by ruthenium complex–tertiary phosphine catalysts to polymers consisting of __trans__‐and __cis__‐olefinic groups and 1,3‐cyclopentylene group. The system derived from dichloro(dodeca‐2,6,10‐triene‐1, 12‐diyl)ruthenium‐(IV) (1) and triphenylphosphine has a fair