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The Polarography of the Nickel Cyanide Complexes and the Solubility and Constitution of Nickel Cyanide 1

✍ Scribed by Hume, David N.; Kolthoff, I. M.

Book ID
121494414
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
505 KB
Volume
72
Category
Article
ISSN
0002-7863

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## Abstract The kinetics and the mechanism of the cyanide‐induced demetallation of a series of Ni^2+^ complexes with macrocyclic ligands of different ring size (12‐ to 14‐membered; see **1**–**4**) and steric constraints was studied. Although the rates differ by almost five orders of magnitude when