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Kinetics of the reaction between cyanide ion and the nickel(II) complexes of iminodiacetate and N-methyliminodiacetate

✍ Scribed by Coombs, Lee C.; Margerum, Dale W.

Book ID
127200480
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
691 KB
Volume
9
Category
Article
ISSN
0020-1669

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Kinetics and Mechanism of the Demetallat
Kinetics and Mechanism of the Demetallation of Macrocyclic Nickel(II) Complexes by Cyanide
✍ Liselotte Siegfried; Thomasβ€…A. Kaden πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 114 KB πŸ‘ 1 views

## Abstract The kinetics and the mechanism of the cyanide‐induced demetallation of a series of Ni^2+^ complexes with macrocyclic ligands of different ring size (12‐ to 14‐membered; see **1**–**4**) and steric constraints was studied. Although the rates differ by almost five orders of magnitude when