The polarographic method of determining rate constants of hydroxyl radicals
✍ Scribed by A. Sobkowiak
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 210 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The relative rate technique has been used to measure the rate coefficient for the reaction of the hydroxyl radical (OH) with methyl isobutyrate (MIB, (CH 3 ) 2 CHC(ϭO)-O-CH 3 ) to be (1.7 Ϯ 0.4) ϫ 10 Ϫ12 cm 3 molecule Ϫ1 s Ϫ1 at 297 Ϯ 3 K and 1 atmosphere total pressure. To more clearly define MIB's
## Abstract The hydrated electron (e^−^~aq~) and hydroxyl radical rate constants with 18 acrylate‐, methacrylate‐, crotonate‐, fumarate‐ and maleate esters are discussed. The constants approach the diffusion‐controlled limit. __k__(e^−^~aq~) and __k__(OH) change in opposite direction; if __k__(e^−^
The relative rate technique has been used to measure the hydroxyl radical (OH) reaction rate constant of ethyl 3-ethoxypropionate (EEP, CH 3 CH 2 -O -CH 2 CH 2 C(O)O -CH 2 CH 3 ). EEP reacts with OH with a bimolecular rate constant of (22.9 Ϯ 7.4) ϫ 10 Ϫ12 cm 3 molecule Ϫ1 s Ϫ1 at 297 Ϯ 3 K and 1 at