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The Polarisation of Double Bonds

✍ Scribed by LAPWORTH, A.; ROBINSON, R.


Book ID
109479586
Publisher
Nature Publishing Group
Year
1923
Tongue
English
Weight
131 KB
Volume
112
Category
Article
ISSN
0028-0836

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πŸ“œ SIMILAR VOLUMES


The polarisabilities of bonds?I
✍ Denbigh, K. G. πŸ“‚ Article πŸ“… 1940 πŸ› Royal Society of Chemistry βš– 833 KB
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✍ R.Alan Aitken; Karamat Ali; Noemı́ de Elena; Philip Lightfoot πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 98 KB

Reaction of the chiral iminium salt 3 with stabilised carbanions gives the compounds 4-9 containing a highly polarised double bond. The extent of this polarisation is determined by variable temperature 1 H NMR studies, comparison of 13 C NMR chemical shifts and an X-ray structure determination.