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Synthesis and structure of highly polarised double-bond compounds derived from S-proline

✍ Scribed by R.Alan Aitken; Karamat Ali; Noemı́ de Elena; Philip Lightfoot

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
98 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reaction of the chiral iminium salt 3 with stabilised carbanions gives the compounds 4-9 containing a highly polarised double bond. The extent of this polarisation is determined by variable temperature 1 H NMR studies, comparison of 13 C NMR chemical shifts and an X-ray structure determination.

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