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ChemInform Abstract: Synthesis and Structure of Highly Polarized Double-Bond Compounds Derived from S-Proline.

✍ Scribed by R. Alan Aitken; Karamat Ali; Noemi de Elena; Philip Lightfoot

Publisher: John Wiley and Sons
Year: 2001
Weight: 28 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200101146

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A Highly Diastereoselective Synthesis of α-Substituted-β-hydroxy Compounds from Corresponding β-Stannyl Compounds. -Anti compounds, e.g. (II), are completely converted to their syn analogues (IV) using Lewis acids such as SnCl 4 or TiCl 4 . AlCl 3 , ZrCl 4 , or ZnCl 2 are not suitable for this reac