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The platinum catalyzed reduction of nitroarenes to aminoarenes with carbon monoxide and water

✍ Scribed by Yoshihisa Watanabe; Yasushi Tsuji; Tatsuya Ohsumi; Ryo Takeuchi

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 111 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)88277-5

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✦ Synopsis

Nitroarenes were readily transformed to aminoarenes in excellent yields under mild conditions with carbon monoxide and water in the presence of a platinum catalyst. Triethylamine, SnC14 and PPh3 are essential for the high catalytic activity. Nitroarenes are reduced chemoselectively by this procedure. Transition metal catalyzed homogeneous water gas shift reaction (WGSR) is

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