Catalytic reduction of nitroaromatics with carbon monoxide and water using tricarbonyltetraphenylcyclopentadienone ruthenium(0)
โ Scribed by Youval Shvo; Dorotha Czarkie
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 666 KB
- Volume
- 368
- Category
- Article
- ISSN
- 0022-328X
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In a batch-autoclave, twenty coals were liquefied using a cobalt-molybdenum oxide catalyst with a mixture of CO and Hz0 at40O"C with or without vehicle oil. Furthermore, lignite and peat were liquefied on tungsten oxide catalyst at 300ยฐC in the absence of CO. The reactivity of coal in this liquefact
Nitroarenes were readily transformed to aminoarenes in excellent yields under mild conditions with carbon monoxide and water in the presence of a platinum catalyst. Triethylamine, SnC14 and PPh3 are essential for the high catalytic activity. Nitroarenes are reduced chemoselectively by this procedure