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The physical basis of the hard/soft acid/base principle

✍ Scribed by Ayers, Paul W.


Book ID
119968365
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
706 KB
Volume
135
Category
Article
ISSN
1359-6640

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When does the Hard and Soft Acid Base pr
✍ Tamer Shoeib; S.I Gorelsky; A.B.P Lever; K.W.M Siu; A.C Hopkinson πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 88 KB

We have studied the silver ion affinities of several R CN ligands using density functional theory. It was found that they correlate linearly with experimental proton affinities, a contradiction to the HSAB principle as H + is a 'hard' acid, and Ag + is a 'soft' acid. This linear correlation between