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The Hard and Soft Acids and Bases Principle

✍ Scribed by Gázquez, José L.


Book ID
119979087
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
108 KB
Volume
101
Category
Article
ISSN
1089-5639

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We have studied the silver ion affinities of several R CN ligands using density functional theory. It was found that they correlate linearly with experimental proton affinities, a contradiction to the HSAB principle as H + is a 'hard' acid, and Ag + is a 'soft' acid. This linear correlation between