The Photosensitised Explosion of Hydrogen-Oxygen Mixtures in the Presence of Chlorine
β Scribed by NORRISH, R. G. W.
- Book ID
- 109495877
- Publisher
- Nature Publishing Group
- Year
- 1931
- Tongue
- English
- Weight
- 243 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/127853a0
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π SIMILAR VOLUMES
The production o f C l 0 0 and C10 radicals following the flash photolysis of chlorine + oxygen mixtures has been studied. For the mechanism the following kinetic parameters were measured: and k:,/c(C100; 250 nm) = 9.7 x 105 cm/sec. Then h:3 = 5.9 X lo9 l/mol.sec, h2 = 1.0 X 10" limol-sec, and t(C
## Abstract The desorption of hydrogen and hydrogen chloride from Si surfaces is the rateβdetermining step of the low temperature CVD of silicon from both hydrogenated and chlorinated precursors. Thus, in order to model the deposition process, the rate of these reactions must be known to a high lev