## Abstract The structure of poly(Lโlysine) containing 44% azobenzene units in the side chain was studied by Xโray diffraction between room temperature and 150ยฐC. The polymer exhibits a mesomorphic structure of the smectic A1 type. In this structure, stable at least until 150ยฐC, each smectic layer
The photoresponse of an azobenzene-containing poly(L-lysine) in the monolayer state
โ Scribed by Benjamin R. Malcolm; Osvaldo Pieroni
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1990
- Tongue
- English
- Weight
- 204 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0006-3525
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Fourier transform ir vibrational circular dichroism (VCD) spectra in the amide I' region of poly(L-lysine) in D,O solutions have confirmed the existence of three distinct conformational states F d an unordered conformational state in this homopolypeptide. Characteristic VCD spectra are presented for
## Abstract Nonenzymatic glycation of macromolecules, especially proteins, takes place mainly due to hyperglycemia in diabetes mellitus. Increased glycolysis during cancer and inflammation during rheumatoid arthritis also contribute to the process of glycation. As lysine residues of proteins are a