✦ LIBER ✦

The photoinduced polar addition of methanol to 2H-pyrroles

✍ Scribed by John M. Patterson; Robert L. Beine; Michael R. Boyd

Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 211 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97325-3

No coin nor oath required. For personal study only.

✦ Synopsis

The direct or sensitized photoinduced Ionic addition of alcohols to cyclohexenes and cycleheptenes but not cyclopentenes is well documented (1,2). Inetead of the addition reaction cyclopentenes undergo either double bond isomerieation and reduction (sensitized photolysis) (3) or polymerization (direct photolyais) (2). Cycloalkenee containing a carbonyl group conjugated with the double bond exhibit similar behavior. While cyclopentenone (4) and cyclohexenone (5) show no evidence for polar addition, cycloheptenoue (6), substituted cyclohexenonee (7), acylcyclohexenones (8) and pyrimidines (9) do. The reported (10) photoreaction of acylcyclopenteues with alcohols probably involves a radical addition since the products are alcohols rather than ethers.

📜 SIMILAR VOLUMES

Photoinduced anti-markovnikov addition o

Photoinduced anti-markovnikov addition of methanol to alkylindenes

✍ Harry Morrison; David Giacherio; Ganesh Pandey 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 157 KB

Irradiation of acidic methanol solutions of several alkylindenes leads to anti-Markovnikov addition of the solvent to the double bond with previously reported pbotoisomerizationa virtually eliminated. We have recently reported on two photoisomerixation reactions of alkylindenee, i.e. phototransposi

The addition of methanol to some bicyclo

The addition of methanol to some bicyclobutanes

✍ William G. Dauben; C.Dale Poulter 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 242 KB

Photoinduced addition of methanol to 5(S

Photoinduced addition of methanol to 5(S)-5-triisopropylsiloxymethyl-N-boc-dihydropyrrole-2(5H)-one: A new route to 4(S), 5(S)-disubstituted pyrrolidin-2-ones

✍ Michael G.B. Drew; R.John Harrison; John Mann; Allen J. Tench; Robert J. Young 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 513 KB

We describe the photoinduced addition of methanol to 5(S)-5-triisopropylsiloxymethyi--N-boc-dihydropyrrole-2(SH)-one to produce 5(S)-5-triisopropylsiloxymethyl-4( S)-hydroxymethylpyrrolidine-2-one, and conversion of this into a variety of 4(S), 5(S)-pyrrolidine-2-ones. Photoinduced addition of metha

ChemInform Abstract: Photoinduced Additi

ChemInform Abstract: Photoinduced Addition of Methanol to 5(S)-5-Triisopropylsiloxymethyl-N-boc-dihydropyrrole-2(5H)-one: A New Route to 4(S), 5(S)-Disubstituted Pyrrolidin-2-ones.

✍ Michael G. B. Drew; R. John Harrison; John Mann; Allen J. Tench; Robert J. Young 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

The photochemical addition of methanol t

The photochemical addition of methanol to acyclic styrenes

✍ Stephen S. Hixson 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 173 KB

ChemInform Abstract: Study of Reactive I

ChemInform Abstract: Study of Reactive Intermediates in Photoinduced Electron Transfer anti-Markovnikov Addition of Methanol to 1-Phenylcycloalkenes.

✍ Masanobu Kojima; Akito Ishida; Yasunao Kuriyama; Yuji Wada; Haruhiko Takeya 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Study of Reactive Intermediates in Photoinduced Electron Transfer anti-Markovnikov Addition of Methanol to 1-Phenylcycloalkenes. -The isomer ratio in the title reaction is investigated for the first time based on mechanistical studies by means of fluorescence spectroscopy, pulse radiolysis and semi