The addition of methanol to some bicyclobutanes
โ Scribed by William G. Dauben; C.Dale Poulter
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 242 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The direct or sensitized photoinduced Ionic addition of alcohols to cyclohexenes and cycleheptenes but not cyclopentenes is well documented (1,2). Inetead of the addition reaction cyclopentenes undergo either double bond isomerieation and reduction (sensitized photolysis) (3) or polymerization (dire
Irradiation of acidic methanol solutions of several alkylindenes leads to anti-Markovnikov addition of the solvent to the double bond with previously reported pbotoisomerizationa virtually eliminated. We have recently reported on two photoisomerixation reactions of alkylindenee, i.e. phototransposi
Observations of the photochemical polar addition of methanol to olefins have hereto-Pore been restricted to cases where the double bond is contained within a ring' or (in a few examples) where an acyclic double bond is conjugated to a highly polar carbonyl grou~.~ We wish to report the anti-Markovni