The high-resolution He 584 A photoelectron spectra of heptafluoroquinoline and heptafluoroisoquinoline are compared with those of the parent compounds. Shifts in ~r ionisation potentials, due to the fluorine substitution, can be described with an inductive and a combined inductive-conjugative Hiicke
The photoelectron spectra of perfluoro-2-butyne and perfluorohexa-2,4-diyne. The perfluorination effect
β Scribed by J.P. Delwiche; M-Th. Praet; G. Caprace; M-J. Hubin-Franskin; P. Natalis; J.E. Collin
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 517 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0368-2048
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## Abstract A tentative assignment is proposed for the He (I__a__) photoelectron (PE.) spectra of the title compounds. It is based on the assumption that the first four Οβbands occupy the same position in both spectra, as suggested by a qualitative correlation with the PE. spectrum of [2~4~](1,2,4,
The C 1s PES of hloz(OzCH)~ and hfo2(02CCH3)4, reported here, show an mtense satelbte peak close to the mam C 1s bne II-us IS assigned, by means of ab mit~o calculations, to a bI (6) + bt (CZpn) transition of the core hole Ion The la& of an mtense satelhte III the 0 1s spectrum IS dncussed.