The photodissociation of SO2+·
✍ Scribed by S.P. Goss; R.G. McLoughlin; J.D. Morrison
- Book ID
- 103600816
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 917 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0168-1176
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In a pulsed molecular beam experiment, cold SOz molecules were generated in a seeded beam. Using the REMPI-TOF technique, detailed investigation of the predissoeiation process SO,(? 'B2) +SO(X 3Z-) + O('P) is possible. First experimental results show that predissociation from specified rovibrational
A molecular beam of SO\* has been photodissociated at I93 nm to measure both the translational energy and angular distributions, from which it is concluded that the photodissociation is predissociative and that the vibrational population is peaked at un =2.
The 193 nm photodissociation of the isotopomers SOz, SO: and SOO' (with O\*= '\*O) was studied by high-resolution photofragment translational spectroscopy. The translational energy distributions P(&) of the fragment pairs SOtO, SO'tff, SOt(T and SO\*+0 were determined from systematic analysis of the