The photodissociation of molecules near the ionisation threshold
β Scribed by G. K. Ivanov; G. V. Golubkov
- Book ID
- 112538086
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 782 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1434-6060
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π SIMILAR VOLUMES
The observed structure in the ionization cross section just above the threshold has been attributed to the formation of auto-ion'zing Rydberg states. The calculation of the auto-ionization rates is discussed in terms of the breakdown rf the Born-Oppenheimer approximation. Three aspects are examined
Excitation functions for Br-and Br+ formation from jet-cooled Br,, in the region 120-I 14 nm (i.e. from threshold to above the ionisation limit of Br2). are reported. The mechanism for ion-pair formation is discussed in terms of homogeneous couphag between the 8pn Rydberg State and the D(O: ) ion-pa