The photodissociation of ClO2: Potential energy surfaces of OClO→Cl+O2
✍ Scribed by Peterson, Kirk A.; Werner, Hans-Joachim
- Book ID
- 121086669
- Publisher
- American Institute of Physics
- Year
- 1996
- Tongue
- English
- Weight
- 701 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.472851
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## Abstract The ClO~3~ many‐body expansion potential energy surface of Farantos and Murrell (__Int J Quantum Chem__ 1978, 14, 659) has been modified along the minimum energy path for the reaction O + OClO → ClO + O~2~ such as to conform with the available kinetics data. The dynamics of the title re
The bimolecular rate constant for the reaction Cl + 03 -Cl0 + O2 is measured over the temperature range 210 to 360 K in it dischare flow system using Cl nfom rcsonzncc fluorescence at 134-72 nm to monitor the decay of Cl under pseudo fist order conditions. Results, expressed in the form k, = (2.35 i