The photodimer of 1-(anthracen-9-ylmethyl)-3-ethylimidazolium iodide
✍ Scribed by Liu, Qing-Xiang ;Song, Hai-bin ;Xu, Feng-bo ;Li, Qing-shan ;Zhang, Zheng-zhi
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 244 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, 9,10 H -bis(3-ethylimidazolium-1-ylmethyl)-9,9 H :10,10 H -bianthracenyl diiodide, was obtained by the photodimerization of 1-(9-anthracenylmethyl)-3-ethylimidazolium iodide. The centrosymmetric crystal structure con®rms that the compound is a head-to-tail dimer.
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## Abstract The IR and __Raman__ spectra and conformations of the ionic liquid 1‐ethyl‐3‐methyl‐1__H__‐imidazolium tetrafluoroborate, [EMIM] [BF~4~] (**6**), were analyzed within the framework of scaled quantum mechanics (SQM). It was shown that SQM successfully reproduced the spectra of the ionic
## Abstract For Abstract see ChemInform Abstract in Full Text.
The calculated and experimental Raman spectra of the (EMI + )TFSI -ionic liquid, where EMI + is the 1-ethyl-3-methylimidazolium cation and TFSI -the bis(trifluoromethanesulfonyl)imide anion, have been investigated for a better understanding of the EMI + and TFSI -conformational isomerism as a functi
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