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The photochemical isomerization of l-acetylbicyclo- [4.1.0]- heptane. An intramoleular rearrement

✍ Scribed by R.E.K. Winter; R.F. Lindauer

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 39 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89987-1

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The kinetics of the gas phase isomerization of l-chloro-4-bromobicyclo[2.2.O]hexane to 2-chloro-5-bromohexa-1,5diene have been measured in a static system over the temperature range of 135-215"C, with a variation in the total pressure from 0.6 to 400 torr. For these conditions, the rate constants ar