Four negative ions. corresponding to successive one-electron addition, of a series of metal ptthalocyanines have been prepared chemically in THF solution. For cobalt (II) phthnlocyanine, five reduction steps arc found. The results of electron spin resonance measurements on these solutions are discus
β¦ LIBER β¦
The photochemical generation of negative phthalocyanine and porphyrin ions
β Scribed by V. G. Maslov; A. N. Sidorov
- Book ID
- 112362763
- Publisher
- Springer
- Year
- 1974
- Tongue
- English
- Weight
- 276 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-5760
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Photochemical irradiation of porphyrins or phthalocyanines with violet or ultraviolet light absorbed by their second or higher absorption bands populates their higher excited states. These higher excited states generally dissipate very rapidly, but, competing with such rapid deactivation, often show