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The photochemical cycloaddition reaction of 2-cyclohexenone with alkenes: Trapping of triplet 1,4-biradical intermediates with hydrogen selenide

โœ Scribed by David J. Maradyn; Alan C. Weedon


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
363 KB
Volume
35
Category
Article
ISSN
0040-4039

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Ultra-violet light irradiation of N-benzoylmdole, 1, m the presence of mono-substituted alkenes results in the formation of cyclobutane adducts of potential synthetic utility.2$3 The reaction is regioselectrve but not stereoselecttve, so that stereoisomers of adduct 3 are formed while 2 is either no