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The Photochemical and Thermal Decomposition of Azidoacetylene in the Gas Phase, Solid Matrix, and Solutions

✍ Scribed by Zeng, Xiaoqing; Beckers, Helmut; Seifert, Jennifer; Banert, Klaus

Book ID
125419771
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
449 KB
Volume
2014
Category
Article
ISSN
1434-193X

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The photolysis of perfluoroglutaryl dichloride was investigated in the gas phase with the light of the full arc of a high pressure mercury lamp. At high intensities and conversions the main products are CO and ClCF&F,CF&l, and the ratio CO/Cl(CF,),Cl is 2. However, in runs with attenuated light and