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The photo-isomerization of stilbene

โœ Scribed by J.B. Birks

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
459 KB
Volume
38
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The SO potential of stilbcne has minima in the trarls (t) and cis (c) confiiuntions and a maximum in the pfrp @) configuration. The St potential has minima at t, p and c due to crossing of the *B, snd t As potentials. and it is proposed that the Tt potential has similar minima due to crossing of the 3B, and "Ag potentials. Five alternative isomerization mecba~sms are considered, tke yields of which depend on eompetirion between vertical radiative and radiationless transitions to lo~r states, and horizontal radiationless transitions betwe% the t, p and c confiiurations of St and Tr . ' ' ':' Vofurne 38; num@r 3

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