The SO potential of stilbcne has minima in the trarls (t) and cis (c) confiiuntions and a maximum in the pfrp @) configuration. The St potential has minima at t, p and c due to crossing of the \*B, snd t As potentials. and it is proposed that the Tt potential has similar minima due to crossing of th
Isomerization of t-stilbene in alcohols
β Scribed by Seong K. Kim; Scott H. Courtney; Graham R. Fleming
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 449 KB
- Volume
- 159
- Category
- Article
- ISSN
- 0009-2614
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We have used a simple Ar+synchronously pumped and cavity-dumped dye-laser system to generate UV picosecond pulses with energies sufficiently high for absorption recovery experiments. With these pulses, we have studied the dynamics of the isomerization of trans-stilbene in n-alcohols as a function of
Stilbene photoisomerizabon is a useful model system for the investigation of condensed phase reaction dynamics. This manuscript presents data on the photoisomerization of meta-methyl-substituted stilbenes in decane as a function of temperature. These kinetic data indicate that the torsional motion a
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