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The phosphorescent triplet state of aniline in a p-xylene host crystal. A study by ESR and MIDP

โœ Scribed by H.M. Van Noort; Ph.J. Vergragt; J. Herbich; J.H. Van Der Waals


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
693 KB
Volume
71
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES


The phosphorescent triplet state of anil
โœ H.M. van Noort; C.A. van't Hof; B. Wirnitzer; J. Schmidt ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 667 KB

It is shown that the spm-spin and spin-lattice relaxation rates in the lowest triplet state of aniline in a p-xylene host crystal are determmed by the presence of a close-lying local phonon state. It is concluded that the motion of the aniline molecule has a highly localised character.

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It is shown that the microwave induced delayed phosphorescence technique can be developed into a very general method. It is possible to measure not only decay rates of the individual spin components of ohosohorescent triplet states as shown in a previous paper. but also the relative radiative decay

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Transient absorption on flash excitation at 308 nm is reported for a K,SO, crystal doped with C&. T'he multi-exponential decay and Its temperature dependence, between 6 and 125 K, support the assi~ment to a metastable triplet state of the CrOj-ion with a fastest decay constant of 200 ns. An experim