The perturbation of the 181Ta quadrupole coupling in tetrakis hafnium (IV) tropolone complex by chloroform

Differential perturbed angular correlati

Differential perturbed angular correlation study of quadrupole coupling of 181Ta in neutral octocoordinated d° hafnium (IV) complexes

✍ P. Boyer; A. Tissier; J.I. Vargas; P. Vulliet 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 488 KB

The diffarential pertutbrd nngulnr correlation of \*'I T:i 133-482 keV y-y cascade was studied in Hf (Iv) d" ncutral complexes. The yuadrupole coupling parameters vvzrc shown to bc sensitive to the noturc of increasingly covalent ligands. The occurrence of several isomcric forms and their intcrconve