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The Perchlorinated Silanes Si2Cl6 and Si3Cl8 as Sources of SiCl2

✍ Scribed by Dipl.-Chem. Frank Meyer-Wegner; Dipl.-Chem. Andor Nadj; Dr. Michael Bolte; Prof. Dr. Norbert Auner; Prof. Dr. Matthias Wagner; Prof. Dr. Max C. Holthausen; Dr. Hans-Wolfram Lerner

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
389 KB
Volume
17
Category
Article
ISSN
0947-6539

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✦ Synopsis

°=

5.1 kcal mol À1 ) for the reaction course; the SiCl 2 complex with the cis-DMB isomer, however, results from IRC calculations to the reactant side.

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Absorption spectra of SiCl4, Si2Cl6, SiF
Absorption spectra of SiCl4, Si2Cl6, SiF3CH3 and GeF4 in the VUV region
✍ Toshio Ibuki; Nobuaki Washida; Uichi Itoh; Yasutake Toyoshima; Hideo Onuki 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 364 KB

In the range 110-200 nm the absorption features of Si#& closely resemble those of SiCl, and the peaks observed are tentatively assigned to the Rydberg transitions of a Cl lone-pair electron. Two diffuse bands in the SiF,CH3 absorption are also assigned to Rydberg excitations. The spectrum of GeF., s