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The Pentacovalent Phosphorus Intermediate of a Phosphoryl Transfer Reaction

✍ Scribed by Lahiri, S. D.

Book ID
119955613
Publisher
American Association for the Advancement of Science
Year
2003
Tongue
English
Weight
371 KB
Volume
299
Category
Article
ISSN
0036-8075

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✍ Jaehoon H. Yu; Wesley G. Bentrude πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 298 KB

Suaraary: A cyclic nucleotide model system (3) for P(V) CAMP-substrate or CAMP-enzyme adducts is shown by 'H NMR analysis to be totally in a twist conformation (3b). The stereochemistry of hydrolysis of CAMP by phosphodiesterases (PDE) has been wellstudied,' as have the structural requirements for t