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The path of the conversion of 3,5,6-tri-O-benzoyl-1,2-O-isopropylidene-?-D-glucose into 4,5,6-tri-O-benzoyl-2,3-di-S-ethyl-2,3-dithio-D-allose diethyl dithioacetal

✍ Scribed by Bethell, G. S.; Ferrier, R. J.


Book ID
118137320
Publisher
Royal Society of Chemistry
Year
1972
Weight
695 KB
Volume
0
Category
Article
ISSN
1472-7781

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The title compound (21) was synthesized from cellobiose as a synthon of a heparin-related oligosaccharide. The per-0-benzyl and per-0-benzoyl derivatives of 1 ,6-anhydro-4-0-(6-deoxy-B-D-~~~lo-hex-5-enopyranosyl)-~-~-glucopyranose were treated with a nonsolvated borane to give a 1 :2 mixture of the