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The palladium (II) acetate promoted 6-endo-trig cyclization of 1,1-dialkyl-2-silyloxy-1,5-dienes.

✍ Scribed by Luz E. Torres; Gerald L. Larson


Book ID
104218574
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
178 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis


Sunmry: A route to cyclohexenones via the treatment of selected ?',&unsaturated enol silyl ethers with palladium (II) acetate is presented.


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ChemInform Abstract: Palladium-Catalyzed
✍ A. BOMBRUN; O. SAGEOT πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 2 views

Palladium-Catalyzed Cyclization of 2-Heteroyl-1-methylene-1,2,3,4tetrahydroisoquinolines. Studies on 6-endo-versus 5-exo-trig Cyclization. -In continuation of an earlier investigation the regioselectivity of the title cyclization is studied. If the corresponding bromide instead of the iodide (IV) i