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The palladium-catalyzed michael addition reaction of the ketone enolates generated by the decarboxylation of allyl β-keto carboxylates under neutral conditions

✍ Scribed by Jnuzo Nokami; Hisayuki Watanabe; Tadakatsu Mandai; Mikio Kawada; Jiro Tsuji

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
354 KB
Volume
30
Category
Article
ISSN
0040-4039

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One-step synthesis of α,β-unsaturated ketones by the reaction of enol acetates with allyl methyl carbonate catalyzed by palladium and tin compounds
✍ Jiro Tsuji; Ichiro Minami; Isao Shimizu 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 115 KB

Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet