A new one-pot method for α,α-diallylation of ketones based on the palladium-catalyzed reaction of allylic carbonates and allyl β-keto carboxylates under neutral conditions

One-step synthesis of α,β-unsaturated ke

One-step synthesis of α,β-unsaturated ketones by the reaction of enol acetates with allyl methyl carbonate catalyzed by palladium and tin compounds

✍ Jiro Tsuji; Ichiro Minami; Isao Shimizu 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 115 KB

Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet