The oxyfunctionalization of cyclohexane catalyzed by Mn(II) complexes included in zeolite Y
β Scribed by F Farzaneh; M Majidian; M Ghandi
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 595 KB
- Volume
- 148
- Category
- Article
- ISSN
- 1381-1169
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β¦ Synopsis
zeolite Y. This oxidation Ε½ .
X was successfully achieved on complex Mn II with ligands of 2,2 -bipyridine, ethylenediamine, tetramethylethylenediamine, and tetramethyl 1,8-naphtalenediamine included in zeolite Y. The enhancement of the conversion percentage from 2.4% to 60% shows that the transition metal complex immobilized on zeolite Y represent a good cytochrome P-450 type oxidation system.
π SIMILAR VOLUMES
In this work we have studied the effect of microwave irradiation in cyclohexane oxidation catalyzed by the Fe(III) complexes: [Fe(BMPA)Cl 3 ] 1, [Fe(MPBMPA)Cl 3 ] 2, [Fe(PBMPA)Cl 2 ] 3 and [Fe(PABMPA)Cl 2 ](ClO 4 ) 4, in acetonitrile as solvent and with H 2 O 2 or t-BuOOH as oxidant. The system was