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The oxyfunctionalization of cyclohexane catalyzed by Mn(II) complexes included in zeolite Y

✍ Scribed by F Farzaneh; M Majidian; M Ghandi


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
595 KB
Volume
148
Category
Article
ISSN
1381-1169

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✦ Synopsis


zeolite Y. This oxidation Ε½ .

X was successfully achieved on complex Mn II with ligands of 2,2 -bipyridine, ethylenediamine, tetramethylethylenediamine, and tetramethyl 1,8-naphtalenediamine included in zeolite Y. The enhancement of the conversion percentage from 2.4% to 60% shows that the transition metal complex immobilized on zeolite Y represent a good cytochrome P-450 type oxidation system.


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Influence of microwave irradiation in th
✍ NakΓ©dia M.F. Carvalho; Heiddy M. Alvarez; Adolfo Horn Jr.; Octavio A.C. Antunes πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 544 KB

In this work we have studied the effect of microwave irradiation in cyclohexane oxidation catalyzed by the Fe(III) complexes: [Fe(BMPA)Cl 3 ] 1, [Fe(MPBMPA)Cl 3 ] 2, [Fe(PBMPA)Cl 2 ] 3 and [Fe(PABMPA)Cl 2 ](ClO 4 ) 4, in acetonitrile as solvent and with H 2 O 2 or t-BuOOH as oxidant. The system was