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Flexible ligand synthesis, characterization and catalytic oxidation of cyclohexane with host (nanocavity of zeolite-Y)/guest (Mn(II), Co(II), Ni(II) and Cu(II) complexes of tetrahydro-salophen) nanocomposite materials

✍ Scribed by Masoud Salavati-Niasari; Maryam Shakouri-Arani; Fatemeh Davar


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
289 KB
Volume
116
Category
Article
ISSN
1387-1811

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Transition metal (M = Mn(II), Co(II), Ni(II) and Cu(II)) complexes with tetradendate Schiff-base ligand; N,N -bis(salicylidene)phenylene-1,3-diamine, H 2 [sal-1,3-phen]; was entrapped in the nanocavity of zeolite-Y by a two-step process in the liquid phase: (i) adsorption of bis(salicylaldiminato)me

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A series of Mn(II), Co(II), Ni(II) and Cu(II) complexes with 12-membered macrocyclic tetradentate ligand; H 6 C 6 N 6 S 2 = 1,2,5,6,8,11hexaazacyclododeca-7,12-dithione-2,4,8,10-tetraene; have been synthesized and characterized as homogeneous and encapsulated into the nanopores of zeolite-Y. These c