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The oxidative coupling of coumaranone with disulfur dichloride

✍ Scribed by Heinz Langhals; Barbara Wagner; Kurt Polborn


Book ID
103402781
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
250 KB
Volume
52
Category
Article
ISSN
0040-4020

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## Abstract Reaction of thiocamphor (I) with disulfur dichloride affords six‐ and seven‐membered tricyclic polysulfanes (II) and (III), respectively, which are oxidized by MCPBA to give bicyclic (E,E)‐α‐disulfine (IV) stereoselectively.