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ChemInform Abstract: Formation of Cyclic Oligosulfides by Reaction of Hydrazones with Disulfur Dichloride.

✍ Scribed by Y.-N. JIN; A. ISHII; Y. SUGIHARA; J. NAKAYAMA

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract Reaction of thiocamphor (I) with disulfur dichloride affords six‐ and seven‐membered tricyclic polysulfanes (II) and (III), respectively, which are oxidized by MCPBA to give bicyclic (E,E)‐α‐disulfine (IV) stereoselectively.